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Download Link CINEMA 4D R21.115 Crack1. Field of the Invention
This invention relates generally to organic chemistry, and more particularly to syntheses of furans and pyrrols.
۲٫ Related Application
This application is the companion case to U.S. patent application Ser. No. 648,836, filed Jan. 4, 1991. The present application includes a historical chemical background.
۳٫ Related Disclosure
I have already filed an application directed to the preparation of 1,3-dihydroxybenzene starting with 2-haloketones. See U.S. Ser. No. 595,820, filed Jul. 21, 1990 and International Application No. PCT/US90/02703, filed Jul. 21, 1990.
۴٫ General Background
I am aware of the following:
Lowe, M. J., et al., J.A.C.S., 1985, 117, 3963, discusses the preparation of furans from hydroxyketones. However, the reaction is conducted in the absence of a base, and no utility is suggested.
I have discovered a practical method to prepare compounds including furans, pyrrols, and pyrroles from appropriate ketones and halocarbonyls. The ketone starting materials include primary and secondary carbon substituted ketones. The basic and neutral organic nucleophiles include lithium, sodium, potassium, tetramethylammonium, 1,8-diazabicyclo[5.4.0]-7-undecene (DBU), pyrrolidine, N-methyl
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